Hydrophobic fumed silica refers to fumed silica nanoparticles that have been surface-treated to exhibit hydrophobic properties. Fumed silica, also known as pyrogenic silica, is a fine powder composed of amorphous silicon dioxide (SiO2) particles that are produced by burning silicon tetrachloride in a flame of hydrogen and oxygen. These nanoparticles have a very high surface area and are highly porous.
The hydrophobic modification of fumed silica involves treating the surface of the nanoparticles with various organic compounds or silanes to make them water-repellent. This modification alters the surface chemistry of the silica particles, reducing their affinity for water. As a result, hydrophobic fumed silica tends to form aggregates or agglomerates in aqueous solutions, rather than dispersing evenly.